Mitsui Chemicals

Special Diamine & Diol

Cycloaliphatic amines,Aromatic amines ,Aromatic phenols,

Usage detail

Epoxy curing agent, polyimide, polyamide, and polyurethane(polyurea),Heat-resistant epoxy resin for a curing agent

Usage

  • Introduction

★★:Commercial manufacturing volume is around 100 kg or less per year
★★★:Now no commercial manufacturing, manufacture volume is a few kg per order.

Cycloaliphatic amines

NBDA/PRO-NBDA is a mixture of 2,5- and 2.6-disubstituents, that has four stereoisomers.
At ambient temperatures, NBDA/PRO-NBDA is low-viscosity liquid having no odor or a slight characteristic odor.
PRO-NBDA is available with competitive price.

NBDA/PRO-NBDA
Norbornanediamine
Bicyclo[2.2.1]heptanebis (methylamine)
Manufacturer; Mitsui Chemicals, Inc.
MFC; Distributor and sole agency
Commercial manufacturing over 1000 ton per year
  • Features
    Colorless and transparent low-viscosity liquid, heat resistance, toughness & high-hardener coating
  • Application
    Epoxy curing agent, polyimide, polyamide, and polyurethane(polyurea)
  • Purity %
    99 Min
  • Appearance NBDA: Clear liquid
    PRO-NBDA: Clear liquid or slightly yellow liquid
  • Freezing point ℃
    NBDA: 5-10, PRO-NBDA: 15-20
  • CAS No.
    56602-77-8
  • TSCA
    Have inventory
  • EINECS/ELINCS
    260-280-7
  • ISHL
    (4)-1732
  • UN
    2735

PRO-NBDA
To start to send the sample; Apr 2014
Commercial launch ; Nov 2014

Aromatic amines -methylene linkage

These monomers are the raw materials of polyimide, polyamide, and a curing agent for epoxy resin. The resin made from these monomers is excellent in heat resistance and mechanical properties (Tg of the resin is higher than Tg of the resin made from aromatic ether diamines).

★★Bisaniline-P
4,4'-(p-Phenylenediisopropylidene)dianiline
Manufacturer; MFC (Toll manufacturing)
  • Features
    The resin made from Bisaniline-P is excellent in heat resistance and mechanical properties.
  • Application
    Polyimide, polyamide, epoxy curing agent
  • Purity %
    99 Min
  • Appearance
    Pale yellow solid
  • Melting point
    164-166 degrees C
  • CAS No.
    2716-10-1
  • TSCA
    Have inventory
  • EINECS/ELINCS
    No inventory
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    (4)-1573
  • ISHL
    7-(4)-759
  • UN
    Not UN Hazardous material
Bisaniline-M
4,4'-(m-Phenylenediisopropylidene)dianiline
Manufacturer; MFC (Toll manufacturing)
  • Features
    The resin made from Bisaniline-M is excellent in heat resistance and mechanical properties.
  • Application
    Polyimide, Polyamides, Epoxy curing agent
  • Purity %
    99 Min
  • Appearance
    Pale yellow solid
  • Melting point
    114-116 degrees C
  • CAS No.
    2687-27-6
  • TSCA
    Have inventory
  • EINECS/ELINCS
    No inventory
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    (4)-1612
  • ISHL
    7-(4)-760
  • UN
    3077

Aromatic amines -sulfone linkage-

These monomers are a curing agent for epoxy resin. The epoxy resin made from these monomers is excellent in heat resistance and flexibility. SO2 is better performance in bonding carbon-fibers.

3,3'-DAS
3,3'-Diaminodiphenylsulfone
MFC; Distributor
  • Features
    The epoxy resin made from 3,3'-DAS is excellent in heat resistance and flexibility.
  • Application
    Heat-resistant epoxy resin for a curing agent
  • Purity %
    99 Min
  • Appearance
    Pale yellow powder
  • Melting point
    171 degrees C
  • CAS No.
    599-61-1
  • TSCA
    Have inventory
  • EINECS/ELINCS
    209-967-5
  • REACH
    applied for the pre-registration
  • ENCS
    (3)-2163
  • ISHL
    (3)-2163
  • UN
    3077
4,4'-DAS
4,4'-Diaminodiphenylsulfone
MFC; Distributor
  • Features
    The epoxy resin made from 4,4'-DAS is excellent in heat resistance and flexibility.
  • Application
    Heat-resistant epoxy resin for a curing agent
  • Purity %
    95 Min
  • Appearance
    Pale yellow powder
  • Melting point
    178 degrees C
  • CAS No.
    80-08-0
  • TSCA
    Have inventory
  • EINECS/ELINCS
    201-248-4
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    (3)-2163
  • ISHL
    (3)-2163
  • UN
    Not UN Hazardous material

Liquid aromatic amines

These monomers are the raw materials of special resins. And, these monomers are a liquid at room temperature, though these are aromatic amines. So, these are excellent in reactivity and handling. Furthermore, the resins made from these monomers are excellent in heat resistance and mechanical properties.

★★ABAm
3-Aminobenzylamine
4-Aminobenzylamine
Manufacturer; MFC (Toll manufacturing)
  • Features
    This amine is excellent in reactivity and handling for epoxy curing agent.
  • Application
    Epoxy curing agent
  • Appearance
    Reddish brown liquid
  • Appearance
    Reddish brown liquid
  • Melting point
    15 degrees C (Max)

50-70wt%

  • CAS No.
    4403-70-7
  • TSCA
    No inventory
  • EINECS/ELINCS
    412-230-2
  • ENCS
    (3)-3897
  • ISHL
    4-(12)-663

50-30wt%

  • CAS No.
    4403-71-8
  • TSCA
    No inventory
  • EINECS/ELINCS
    610-164-0
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    (3)-3897
  • ISHL
    4-(12)-663
  • UN
    2735

Aromatic phenols

These monomers are key monomers in the production of epoxy resins and polycarbonate plastic. These monomers have excellent mechanical properties.

BPF-SG
Methylenebisphenol
Manufacturer; Japanese chemical company
MFC; Agency for exporting
Commercial manufacturing about 1000 ton per year
  • Features
    This BPF-SG is the speicial Bisphenol-F, that is High purity type of Bisphenol-F. By using BPF-SG, you can easily make high molecular weight epoxy polymer without gelation.
  • Application
    Epoxy resins
  • Purity %
    99 Min
  • Appearance
    White solid
  • Melting point
    100 degrees C
  • REACH
    Now we are going to study about the pre-registration

BPF-SG is a mixture of three compounds; 4-4 Methylenebisphenol, and 4-4 Methylenebisphenol, and 2-2 Methylenebisphenol.

  • 4,4'-Methylenebisphenol:Cas#620-92-8 27-33wt%
  • 2,4'-Methylenebisphenol:Cas#2467-03-0 48-52wt%
  • 2,2'-Methylenebisphenol:Cas#2467-02-9 17-20wt%
CAS No. 620-92-8 2467-03-0 2467-02-9
TSCA Have inventory Have inventory Have inventory
EINECS/ELINCS 210-658-2 219-579-8 219-578-2
EINECS/ELINCS (4)-90 (7)-9038 (7)-903
ISHL (4)-90 (7)-9038 (7)-903
Bisphenol-M
4,4'-(m-Phenylenediisopropyridene)diphenol
Manufacturer; MFC (Toll manufacturing)
  • Features
    The polymer made from Bisphenol-M is excellent in mechanical properties.
  • Application
    Special resins
  • Purity %
    99 Min
  • Appearance
    White powder
  • Melting point
    137-141 degrees C
  • CAS No.
    13595-25-0
  • TSCA
    Have inventory
  • EINECS/ELINCS
    428-970-4
  • REACH
    Registered
  • ENCS
    (4)-1582
  • ISHL
    7-(4)-1044
  • UN
    3077
★★Bisphenol-P
4,4'-(p-Phenylenediisopropyridene)diphenol
image4,4'-(p-Phenylenediisopropyridene)diphenol
  • Features
    The polymer made from Bisphenol-P is excellent in mechanical properties and heat resistance.
  • Application
    Special resins
  • Purity %
    99 Min
  • Appearance
    White powder
  • Melting point
    192-196 degrees C
  • CAS No.
    2167-51-3
  • TSCA
    NO inventory
  • EINECS/ELINCS
    606-820-0
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    (4)-1538
  • ISHL
    7-(4)-791
  • UN
    3077
★★Bisxylenol-P
4,4'-[1,4-Phenylenebis(1-methylethylydene)]bis(2,6-dimethylphenol)
Manufacturer; MFC (Toll manufacturing)
  • Features
    The polymer made from Bisxylenol-P is excellent in mechanical properties.
  • Application
    Resin reforming agent
  • Purity %
    99 Min
  • Appearance
    White powder
  • Melting point
    157-163 degrees C
  • CAS No.
    36395-57-0
  • TSCA
    NO inventory
  • EINECS/ELINCS
    No inventory
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    No inventory
  • ISHL
    7-(4)-840
  • UN
    Not UN Hazardous material

Chain extender for polyurethane

BHEB
1,4-Bis(2-hydroxyethoxy)benzene
Manufacturer; MFC (Toll manufacturing)
  • Features
    Polyurethane elastomers obtained by the use of BHEB is excellent in mechanical properties.
  • Application
    Chain extender for polyurethane elastomers(TPU)
  • Purity %
    96 Min
  • Appearance
    White flake
  • Melting point
    102-106 degrees C
  • CAS No.
    104-38-1
  • TSCA
    Have inventory
  • EINECS/ELINCS
    203-197-3
  • REACH
    applied for the pre-registration
  • ENCS
    (3)-642
  • ISHL
    (3)-642
  • UN
    Not UN Hazardous material
DER
1,3-Bis(2-hydroxyethoxy)benzene
Manufacturer; MFC (Toll manufacturing)
  • Features
    Polyurethane elastomers obtained by the use of DER is excellent in mechanical properties.
  • Application
    Chain extender for polyurethane elastomers(TPU)
  • Purity %
    98 Min
  • Appearance
    White to pale brown flake
  • Melting point
    90 degrees C
  • CAS No.
    102-40-9
  • TSCA
    Have inventory
  • EINECS/ELINCS
    203-028-3
  • REACH
    will apply for the pre-registration
  • ENCS
    (3)-3864
  • ISHL
    4-(10)-409
  • UN
    Not UN Hazardous material

Epoxy derivatives

★★★TG-NBDA
Epoxy resins made by NBDA
Manufacturer; MFC (Toll manufacturing)
  • Features
    Liquid type of tetraglycidyl epoxy resins
  • Application
    CFRP, electronic materials, epoxy resins)
  • Appearance Pale yellow liquid
  • Viscosity
    3～6 Pa・s(25℃)
  • CAS No.
    No inventory8
  • TSCA
    No inventory
  • EINECS/ELINCS
    No inventory
  • REACH
    Now we have no plan for REACH registration
  • ENCS
    No inventory
  • ISHL
    No inventory
  • UN
    Not UN Hazardous material

Aromatic Ether Diaminess

APB-N
1,3-Bis(3-aminophenoxy) benzene
  • Features
    Lower cost than APB
  • Application
    Heat-resistant resin, varnish and adhesive
  • Purity %
    97 Min
  • Appearance Pale brown fine granule
  • Melting point
    107-110 degrees C
  • CAS No.
    10526-07-5
  • TSCA
    inventory
  • EINECS/ELINCS
    234-082-6
  • ENCS
    (3)-3948
  • ISHL
    4-(14)-179

Contact Us
Contact Form

MITSUI CHEMICALS AMERICA, INC.
TEL+1 914-253-0777
FAX+1 914-253-0790